Direct Hydroxylation of Benzene Over Cu-Exchanged Hydroxy-Sodalite
نویسندگان
چکیده
منابع مشابه
A Computational Study on the Aerobic Oxidation of Benzene to Phenol in Cu/Exchanged Y Zeolite
In heterogeneous catalysis transition metal-containing zeolites, in particular copperexchanged zeolites, have been studied experimentally [1, 2] as well as theoretically. Zeolites have large surface areas and different active sites (Brønsted acid sites and transition metal centers) which play a significant role in catalysis. In order to study the catalytic oxidation of benzene to phenol using d...
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The main goal of this work was to synthesize and evaluate the effect of dehydration temperature on the potential application of hydroxy sodalite zeolite membrane. Hydroxy sodalite zeolite membranes were synthesized via direct hydrothermal method onto a tubular alumina support without seeding in a hot air oven. The synthesized membranes were characterized by X-ray diffraction (XRD) and scanning ...
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Vanadium supported on highly ordered nanoporous silica (VOx-LUS-1) was synthesized and characterized by XRD, Nitrogen adsorption‑desorption isotherms and UV-visible spectrophotometer. Direct oxidation of benzene to phenol in liquid phase by H2O2 peroxide were examined by using various solvents (methanol, acetone, acetic acid, acetonitryl). The maximum yield (25%) and selectivity (73%) of the ph...
متن کاملIron(III) complexes of multidentate pyridinyl ligands: synthesis, characterization and catalysis of the direct hydroxylation of benzene.
Three multidentate ligands, L₁-L₃, derived from bis(pyridin-2-ylmethyl)amine (L₁) were synthesized. Reaction of these ligands with FeCl3·6H2O in methanol led to the formation of the iron complexes Fe₁-Fe₃ (Fe₁: [FeL₁Cl3]; Fe₂: [FeL₂Cl3]; Fe₃: [FeL₃Cl3]) in good yields. These complexes have been fully characterized. The structures of complexes Fe₁-Fe₃ have been determined using X-ray single crys...
متن کاملSynthesis and characterization of copper(ii) complexes with multidentate ligands as catalysts for the direct hydroxylation of benzene to phenol.
Four copper(ii) complexes with multidentate ligands, ([CuL1Cl2]), ([Cu(HL2)Cl2]), ([Cu2(L2)2](ClO4)2) and ([CuL3(HOCH3)ClO4]) {L1 = N,N-bis((pyridin-2-yl)methyl) prop-2-yn-1-amine, HL2 = 2-((((1-methyl-1H-imidazol-2-yl)methyl)(pyridin-2-ylmethyl)amino)methyl)phenol and HL3 = 2-((((1-methyl-1H-imidazol-2-yl)methyl)(pyridin-2-ylmethyl)amino)methyl)-2-t-butyl-phenol} are reported. The complexes we...
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ژورنال
عنوان ژورنال: Egyptian Journal of Chemistry
سال: 2018
ISSN: 2357-0245
DOI: 10.21608/ejchem.2018.2744.1221